Published Resources Details

Journal Article

Author
Robson, Richard
Title
Complexes of binucleating ligands. II. Geometrical models for potential nitrogen fixing systems
In
Australian Journal of Chemistry
Imprint
vol. 23, no. 11, CSIRO Publishing, Canberra, 1970, pp. 2217-2224
Url
https://doi.org/10.1071/CH9702217c
Format
pdf
Contains
Image
Abstract

The synthesis and some properties of a series of complexes, LCu2(X), are discussed where L is the binucleating trianion derived from d-methylisophthal-aldehyde di-2'-hydroxyanil [2-hydroxy-5-methyl-1,3-xylene-¿,¿'-diylidenebis(2-hydroxyphenylamine)] and X- is OH-, OR- ; pyrazolate anion; binuclear structures are assigned to these compounds on the basis of spectral and magnetic evidence. In the compound formulated as (L,H2O)Cu2(OCH3) it is suggested that the water molecule is added across one Schiff base link in L. The possible relevance of the results to a long-term project concerned with the synthesis of potential nitrogen-fixing systems is briefly discussed.

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Related Published resources

isRelated

  • Pilkington, N. H.; Robson, Richard, 'Complexes of binucleating ligands. III. Novel complexes of a macrocyclic binucleating ligand', Australian Journal of Chemistry, 23 (11) (1970), 2225-2236, https://doi.org/10.1071/CH9702225. Details

EOAS ID: bib/ASBS17657.htm

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